論文リスト

71.  “Iron-Catalysed Regioselective Thienyl C–H/C–H Coupling”
 T. Doba, L. Ilies, W. Sato, R. Shang,* E. Nakamura,* Nat. Catal. 2021, 4, 631–638. 

 

70.  “Ligand-Enabled, Iridium-Catalyzed ortho-Borylation of Fluoroarenes”
 O. Kuleshova, S. Asako, L. Ilies,* ACS Catal. 2021, 11, 5968–5973.  

 
69.  “Halogen–Sodium Exchange Enables Efficient Access to Organosodium Compounds”
 S. Asako,* I. Takahashi, H. Nakajima, L. Ilies, K. Takai,* Commun. Chem. 20214, 76 (ChemRxiv. 2020 doi: 10.26434/chemrxiv.12378104.v1). Highlighted in Nature Reviews Chemistrylink  

 
68.  “Recent Advances in the Use of Sodium Dispersion for Organic Synthesis”
 P. B. De, S. Asako,* L. Ilies,* Synthesis 2021, 53, 3180–3192 (invited short review to the “Bond Activation - in Honor of Prof. Shinji Murai” special issue). 

 

67. “Molybdenum‐Catalyzed Deoxygenative Cyclization of Carbonyl Compounds for the Synthesis of Pyrido[2,1‐a]isoindoles”
 S. Asako,* T. Kobayashi, S. Ishihara, K. Takai,* Asian J. Org. Chem. 2021, 10, 753–756 (invited contribution to the “Early Career Researchers Special Collection”). 

 

66.  “C–H Activation Catalyzed by Earth-Abundant Metals”
 L. Ilies,* Bull. Chem. Soc. Jpn. 2021, 94, 404–417 (invited account to the “Frontiers of Molecular Science” Diamond Collection issue). inside cover

 

65.  “Negatively Curved Nanographene with Heptagonal and [5]Helicene Units”
 Z. Qiu, S. Asako,* Y. Hu, C.-W. Ju, T. Liu, J.-S. Lauret, K. Müllen,* A. Narita,* J. Am. Chem. Soc. 2020, 142, 14814–14819. 

 

64.  “Olefin Synthesis by Deoxygenative Coupling of Carbonyl Compounds: From Stoichiometric to Catalytic”
 S. Asako,* L. Ilies,* Chem. Lett. 202049, 1386-1393 (highlight review).  back cover picture

  

63.  “Earth‐Abundant Metals in Catalysis”
 L. Ilies,* S. P. Thomas,* I. A. Tonks,* Asian J. Org. Chem. 20209, 324-325 (special issue editorial).
 
62.  “Chromium(III)-Catalyzed C(sp2)–H Alkynylation, Allylation, and Naphthalenation of Secondary Amides with Trimethylaluminum as Base”
 M. Chen, T. Doba, T. Sato, H. Razumkov, L. Ilies, R. Shang,* E. Nakamura,* J. Am. Chem. Soc. 2020, 142, 4883–4891. 

 

61.  「C-H結合活性化反応」 イリエシュ ラウレアン,浅子 壮美,吉田 拓未,化学要点シリーズ,34巻,共立出版 (2019年).

 

 
60.  “Deoxygenative Insertion of Carbonyl Carbon into a C(sp3)–H Bond: Synthesis of Indolines and Indoles”
 S. Asako,* S. Ishihara, K. Hirata, K. Takai,* J. Am. Chem. Soc. 2019, 141, 9832–9836. 

 
 

59.  “Lithium‐Free Synthesis of Sodium 2,2,6,6‐Tetramethylpiperidide and Its Synthetic Applications”
 S. Asako,* M. Kodera, H. Nakajima, K. Takai,* Adv. Synth. Catal. 2019, 361, 3120–3123. 

 

58.  “Organosodium Compounds for Catalytic Cross-Coupling”
 S. Asako,* H. Nakajima, K. Takai,* Nat. Catal. 2019, 2, 297–303. Highlighted in News & ViewsC&ENChemistry World.

 

57.  “Homocoupling-Free Iron-Catalysed Twofold C–H Activation/Cross-Couplings of Aromatics via Transient Connection of Reactants”
 T. Doba, T. Matsubara, L. Ilies, R. Shang,* E. Nakamura,* Nat. Catal. 2019, 2, 400–406. 

 
 

56.  “Iron-Catalyzed Directed Alkylation of Carboxamides with Olefins via a Carbometalation Pathway”
 L. Ilies,* Y. Zhou, H. Yang, T. Matsubara, R. Shang, E. Nakamura,* ACS Catal. 2018, 811478–11482.

 

55.  “Synthesis of Esomeprazole and Related Proton Pump Inhibitors through Iron-Catalyzed Enantioselective Sulfoxidation”
 S. Nishiguchi,* T. Izumi, T. Kouno, J. Sukegawa, L. Ilies,* E. Nakamura,* ACS Catal. 2018, 8, 9738−9743.

 

54.  “Silylation of Aryl Halides with Monoorganosilanes Activated by Lithium Alkoxide”
 T. Yoshida, L. Ilies,* E. Nakamura,* Org. Lett. 201820, 2844-2847.

 

53.  “Iron-Catalyzed Synthesis of Indenones through Cyclization of Carboxamides with Alkynes”
Laurean Ilies,* Yasin Arslanoglu, Tatsuaki Matsubara, Eiichi Nakamura,* Asian J. Org. Chem. 20187, 1327-1329. (invited contribution to a special issue on C–H activation).

 

52.  “Iron-Catalyzed Remote Arylation of Aliphatic C-H Bond via 1,5-Hydrogen Shift”
Bingwei Zhou, Hiroki Sato, Laurean Ilies,* Eiichi Nakamura,* ACS Catal. 2018, 8, 8–11. [highlighted in SYNFACTS 2018, 184]

 

51.  “Manganese-Catalyzed Directed Methylation of C(sp2)–H Bonds at 25 °C with High Catalytic Turnover”
Takenari Sato, Takumi Yoshida, Hamad H. Al Mamari, Laurean Ilies,* Eiichi Nakamura,* Org. Lett. 2017, 19, 5458–5461.
 

 
50.  “Iron-Catalyzed Borylation of Aryl Chlorides in the Presence of Potassium t-Butoxide”
Takumi Yoshida, Laurean Ilies,* Eiichi Nakamura,* ACS Catal. 2017, 7, 3199–3203. [highlighted in SYNFACTS, 2017, 13, 639]

 

49.  “Indole Synthesis via Cyclative Formation of 2,3-Dizincioindoles and Regioselective Electrophilic Trapping”
Laurean Ilies,* Mayuko Isomura, Shin-ichi Yamauchi, Tomoya Nakamura, Eiichi Nakamura,* J. Am. Chem. Soc. 2017, 139, 23–26. [highlighted in SYNFACTS, 2017, 13, 245] 

 

48.  “Iron/Zinc-Cocatalyzed Directed Arylation and Alkenylation of C(sp3)-H Bonds with Organoborates”
Laurean Ilies,* Yuki Itabashi, Rui Shang, Eiichi Nakamura,* ACS Catal. 2017, 7, 89–92. [highlighted in SYNFACTS, 2017, 7, 89]

47.  “Iron-Catalyzed C–H Bond Activation”
Laurean Ilies,* Journal of Organic Synthetic Chemistry, Japan 2017, 75, 802–809 (award account).
   
46.  “Iron-Catalyzed C–H Bond Activation”
Rui Shang, Laurean Ilies,* Eiichi Nakamura,* Chem. Rev. 2017, 117, 9086–9139 (invited contribution to a special issue on C–H activation).

Rui Shang, Laurean Ilies,* Eiichi Nakamura,* J. Am. Chem. Soc. 2016, 138, 10132–10135. 

44.  “Oxidative C–H Activation Approach to Pyridone and Isoquinolone via Iron-Catalyzed Coupling of Amide with Alkyne”
Tatsuaki Matsubara, Laurean Ilies,* Eiichi Nakamura,* Chem. Asian J. 2016, 11, 380–384. (invited contribution to “Catalysis and Transformation of Complex Molecules” special issue).

43.  “Iron-Catalyzed C–H Bond Activation”
Laurean Ilies,* Eiichi Nakamura, Topics in Organometallic Chemistry: C-H Bond Activation and Catalytic Functionalization II, Eds.: P. H. Dixneuf and H. Doucet, pp 1-18, Springer Berlin Heidelberg (2016).
   
42.  “Iron-Catalyzed Directed C(sp2)–H and C(sp3)–H Functionalization with Trimethylaluminum”
Rui Shang, Laurean Ilies,* Eiichi Nakamura,* J. Am. Chem. Soc. 2015, 137, 7660–7663 [highlighted in SYNFACTS, 2015, 969, and chosen Synfact of the Month].

41.  “Iron-Catalyzed Directed Alkylation of Alkenes and Arenes with Alkylzinc Halides”
Laurean Ilies,* Saki Ichikawa, Sobi Asako, Tatsuaki Matsubara, Eiichi Nakamura,* Adv. Synth. Catal. 2015, 357, 2175–2179 (Very Important Publication, invited contribution to the special issue dedicated to Stephen L. Buchwald). 

40.  “Iron-Catalyzed C(sp2)–H Bond Functionalization with Organoboron Compounds”
Rui Shang, Laurean Ilies,* Sobi Asako, Eiichi Nakamura,* J. Am. Chem. Soc. 2014, 136, 14349–14352. 

39.  “Iron-Catalyzed Directed Alkylation of Aromatic and Olefinic Carboxamides with Primary and Secondary Alkyl Tosylates, Mesylates, and Halides”
Laurean Ilies,* Tatsuaki Matsubara, Saki Ichikawa, Sobi Asako, Eiichi Nakamura,* J. Am. Chem. Soc. 2014, 136, 13126–13129. 

38.  “ortho-Allylation of 1-Arylpyrazoles with Allyl Phenyl Ether via Iron-catalyzed C–H Bond Activation under Mild Conditions”
Sobi Asako, Jakob Norinder, Laurean Ilies,* Naohiko Yoshikai, Eiichi Nakamura,* Adv. Synth. Catal. 2014, 356, 1481–1485 (invited contribution to the Directed C–H Activation thematic issue, Ed. J.-Q. Yu).

 

37.  “Theoretical Study on Alkoxydiphosphine Ligand for Bimetallic Cooperation in Nickel-Catalyzed Monosubstitution of C–F Bond”
Sobi Asako, Laurean Ilies,* Pritha Verma, Saki Ichikawa, Eiichi Nakamura,* Chem. Lett. 2014, 43, 726–728.

36.  “Synthesis of Anthranilic Acid Derivatives through Iron-Catalyzed Ortho Amination of Aromatic Carboxamides with N-Chloroamines”
Tatsuaki Matsubara, Sobi Asako, Laurean Ilies,* Eiichi Nakamura,* J. Am. Chem. Soc. 2014, 136, 646–649. [highlighted in SYNFACTS, 2014, 408]

35.  “Synthesis of Polysubstituted Enynes via Iron-Catalyzed Carbomagnesiation of Conjugated Diynes”
Laurean Ilies, Takumi Yoshida, Eiichi Nakamura,* Synlett 2014, 25, 527–530.

34.  “Iron Catalysis for Organic Synthesis” (translation from the Japanese)
Laurean Ilies, Eiichi Nakamura, in Iron Dictionary, Chapter 8.9.2, pp 234–241, Asakura Publishing Co. (2014).
 
33.  “Synthetic Strategy for Multisubstituted Fused Furan Compounds Using Main-Group Metal Reagents”
Hayato Tsuji,* Laurean Ilies, Eiichi Nakamura,* Synlett 2014, 25, 2099–2110.
 
32.  “Iron-Catalyzed Cross-Coupling Reactions”
Laurean Ilies, Eiichi Nakamura,* in The Chemistry of Organoiron Compounds, Eds.: I. Marek and Z. Rappoport, pp 539–567, John Wiley&Sons, Ltd.: Chichester, UK (2014).
 
31.  “Iron-Catalyzed Cross-Coupling Reactions”,
Eiichi Nakamura,* Takuji Hatakeyama, Shingo Ito, Kentaro Ishizuka, Laurean Ilies, Masaharu Nakamura in Organic Reactions, vol. 83, pp 1–209, Ed.: S. E. Denmark, John Wiley&Sons, Inc. (2014).
 
30.  “Iron-Catalyzed Ortho-Allylation of Aromatic Carboxamides with Allyl Ethers”
Sobi Asako, Laurean Ilies,* Eiichi Nakamura,* J. Am. Chem. Soc. 2013, 135, 17755–17757. [highlighted in SYNFACTS, 2014, 190]

 
29.  β-Arylation of Carboxamides via Iron-Catalyzed C(sp3)–H Bond Activation”
Rui Shang, Laurean Ilies, Arimasa Matsumoto, Eiichi Nakamura,* J. Am. Chem. Soc. 2013, 135, 6030–6032. [highlighted in SYNFACTS, 2013, 771]

 
28.  “Iron-Catalyzed Allylic Arylation of Olefins via C(sp3)–H Activation under Mild Conditions”
Masaki Sekine, Laurean Ilies, Eiichi Nakamura,* Org. Lett. 2013, 15, 714–717. [highlighted in SYNFACTS, 2013, 433]

 
27.  “Nickel-Catalyzed Synthesis of Diarylamines via Oxidatively Induced C–N Bond Formation at Room Temperature”
Laurean Ilies, Tatsuaki Matsubara, Eiichi Nakamura,* Org. Lett. 2012, 14, 5570–5573.

  

26.  “Iron-Catalyzed Chemo- and Stereoselective Hydromagnesiation of Diarylalkynes and Diynes”
Laurean Ilies, Takumi Yoshida, Eiichi Nakamura,* J. Am. Chem. Soc. 2012, 134, 16951–16954. [highlighted in SYNFACTS, 2013, 88]

25.  “Synthesis of Polysubstituted Naphthalenes by Iron-Catalyzed [2 + 2 + 2] Annulation of Grignard Reagents with Alkynes”
Laurean Ilies, Arimasa Matsumoto, Motoaki Kobayashi, Naohiko Yoshikai, Eiichi Nakamura,* Synlett 2012, 23, 2381–2384.

 

24.  “Iron-Catalyzed ortho Monoarylation of Benzamide Derivatives"
Laurean Ilies, Eita Konno, Quan Chen, Eiichi Nakamura,* Asian J. Org. Chem 2012, 1,142–145.

 
23.  “Nickel-Catalyzed Monosubstitution of Polyfluoroarenes with Organozinc Reagents Using Alkoxydiphosphine Ligand”
Yuki Nakamura, Naohiko Yoshikai, Laurean Ilies, Eiichi Nakamura,* Org. Lett. 2012, 14, 3316–3319. [highlighted in SYNFACTS, 2012, 1007]

  

22.  “Iron-Catalyzed Regio- and Stereoselective Chlorosulfonylation of Terminal Alkynes with Aromatic Sulfonyl Chlorides”
Xiaoming Zeng, Laurean Ilies, Eiichi Nakamura,* Org. Lett. 2012, 14, 954–956.

21.  “Iron-Catalyzed Nitrogen-Directed Coupling of Arene and Aryl Bromides Mediated by Metallic Magnesium”
Laurean Ilies, Motoaki Kobayashi, Arimasa Matsumoto, Naohiko Yoshikai, Eiichi Nakamura,* Adv. Synth. Catal. 2012, 354, 593–596.

 
20.  “Iron-Catalyzed Direct Functionalization of Inert C–H Bonds”
Laurean Ilies,* Eiichi Nakamura,* Fine Chemicals 2012, 41, 40–45.
  
19.  “Synthesis of Functionalized 1H-Indenes via Copper-Catalyzed Arylative Cyclization of Arylalkynes with Aromatic Sulfonyl Chlorides”
Xiaoming Zeng, Laurean Ilies, Eiichi Nakamura,* J. Am. Chem. Soc. 2011, 133, 17638–17640.

  
18.  “Iron-Catalyzed Oxidative Monoarylation of Primary Amines with Organozinc Reagents”
Yuki Nakamura, Laurean Ilies, Eiichi Nakamura,* Org. Lett. 2011, 13, 5998–6001. [highlighted in SYNFACTS, 2012, 199]

  

17.  “Iron-Catalyzed C–H Bond Activation for the ortho-Arylation of Aryl Pyridines and Imines with Grignard Reagents"
Naohiko Yoshikai, Sobi Asako, Takeshi Yamakawa, Laurean Ilies, Eiichi Nakamura,* Chem. Asian J. 2011, 6, 3059–3065.

16.  “Cobalt-Catalyzed Coupling of Alkyl Grignard Reagent with Benzamide and 2-Phenylpyridine Derivatives through Directed C–H Bond Activation under Air"
Quan Chen, Laurean Ilies, Naohiko Yoshikai, Eiichi Nakamura,* Org. Lett. 2011, 13, 3232–3234. [highlighted in SYNFACTS, 2011, 1008]

 

15.  “Iron-Catalyzed Stereospecific Activation of Olefinic C–H Bonds with Grignard Reagent for Synthesis of Substituted Olefins”
Laurean Ilies, Sobi Asako, Eiichi Nakamura,* J. Am. Chem. Soc. 2011, 133, 7672–7675. [highlighted in SYNFACTS, 2011, 896]

 
14. “Phenanthrene Synthesis by Iron-Catalyzed [4 + 2] Benzannulation between Alkyne and Biaryl or 2-Alkenylphenyl Grignard Reagent”
Arimasa Matsumoto, Laurean Ilies, Eiichi Nakamura,* J. Am. Chem. Soc. 2011, 133, 6557–6559. [highlighted in SYNFACTS, 2011, 774]

13. “Cobalt-Catalyzed Chemoselective Insertion of Alkene into the Ortho C−H Bond of Benzamide”
Laurean Ilies, Quan Chen, Xiaoming Zeng, Eiichi Nakamura,* J. Am. Chem. Soc. 2011, 133, 5221–5223.

 
12. “Cobalt-Catalyzed ortho-Alkylation of Secondary Benzamide with Alkyl Chloride through Directed C–H Bond Activation”
Quan Chen, Laurean Ilies, Eiichi Nakamura,* J. Am. Chem. Soc. 2011, 133, 428–429. [highlighted in SYNFACTS 2011, 7, 433]

11. “Iron-Catalyzed, Directed Oxidative Arylation of Olefins with Organozinc and Grignard Reagents”
Laurean Ilies, Jun Okabe, Naohiko Yoshikai, Eiichi Nakamura,* Org. Lett. 2010, 12, 2838–2840. [highlighted in SYNFACTS 2010, 1053]

 
10. “Iron-Catalyzed C−C Bond Formation at a-Position of Aliphatic Amines via C−H Bond Activation through 1,5-Hydrogen Transfer”
Naohiko Yoshikai, Adam Mieczkowski, Arimasa Matsumoto, Laurean Ilies, Eiichi Nakamura,* J. Am. Chem. Soc. 2010, 132, 5568–5569. [highlighted in SYNFACTS 2010, 820]

 
9. “Synthesis of Tetrasubstituted Alkenes by Stereo- and Regioselective Stannyllithiation of Diarylacetylenes”
Hayato Tsuji,* Yasuyuki Ueda, Laurean Ilies, Eiichi Nakamura,* J. Am. Chem. Soc. 2010, 132, 11854–11855. [highlighted in SYNFACTS 2010, 1257, also selected "SYNFACT of the month"]

 

8. “Modular Synthesis of Polybenzo[b]silole Compounds for Hole-Blocking Material in Phosphorescent Organic Light Emitting Diodes”
Laurean Ilies, Yoshiharu Sato,* Chikahiko Mitsui, Hayato Tsuji,* Eiichi Nakamura,* Chem. Asian J. 2010, 5, 1376–1381.

 
7. “Synthesis of Benzo[b]siloles via KH-Promoted Cyclization of (2-Alkynylphenyl)silanes”
Laurean Ilies, Hayato Tsuji,* Eiichi Nakamura,* Org. Lett. 2009, 11, 3966–3968.

 
6. “Tetraaryl-substituted Benzo[1,2-b:4,5-b']dipyrroles: Synthesis, Properties, and Applications to Hole-Injection Materials in OLED Devices”
Hayato Tsuji,* Yuki Yokoi, Chikahiko Mitsui, Laurean Ilies, Yoshiharu Sato, Eiichi Nakamura,* Chem. Asian J. 2009, 4, 655–657.

5. “Modular Synthesis of Benzo[b]phosphole Derivatives via BuLi-Mediated Cyclization of (o-Alkynylphenyl)phosphine”
Hayato Tsuji,* Kosuke Sato, Laurean Ilies, Yoshimitsu Itoh, Yoshiharu Sato, Eiichi Nakamura,* Org. Lett. 2008, 10, 2263–2265.

 
4. “Modular Synthesis of Functionalized Benzosiloles by Tin-mediated Cyclization of (o-Alkynylphenyl)silane”
Laurean Ilies, Hayato Tsuji,* Yoshiharu Sato, Eiichi Nakamura,* J. Am. Chem. Soc. 2008, 130, 4240–4241 [highlighted in SYNFACTS 2008, 702]

3. "Synthesis and Properties of 2,3,6,7-Tetraarylbenzo[1,2-b:4,5-b’]difurans as Hole-Transporting Material"
Hayato Tsuji,* Chikahiko Mitsui, Laurean Ilies, Yoshiharu Sato, Eiichi Nakamura,* J. Am. Chem. Soc. 2007, 129, 11902–11903.

2. “2,3-Disubstituted Benzofuran and Indole by Copper-Mediated C–C Bond Extension Reaction of 3-Zinciobenzoheterole”
Masaharu Nakamura,* Laurean Ilies, Saika Otsubo, Eiichi Nakamura,* Org. Lett2006, 8, 2803–2805. [highlighted in SYNFACTS 2006, 832]

1. “3-Zinciobenzofuran and 3-Zincioindole: Versatile Tools for Construction of Conjugated Structures Containing Multiple Benzoheterole Units”
Masaharu Nakamura,* Laurean Ilies, Saika Otsubo, Eiichi Nakamura,* Angew. Chem. Int. Ed. 200645, 944–947. [highlighted in SYNFACTS 2006, 427]